Modification of Porous Composite Material ZIF-67/Chitosan as Methyl Orange Dye Absorbent

Modifikasi Material Komposit Berpori ZIF-67/Kitosan sebagai Penyera Zat Warna Metil Jingga

Authors

  • Dety oktavia Sulistiono Engineering Department, Politeknik Negeri
  • Jumiatun Politeknik Negeri Jember
  • Badrut Tamam Ibnu Ali National Research and Innovation Agency, B.J. Habibie Building, Central Jakarta, Indonesia

Keywords:

Adsorpsi, Komposit, kitosan, ZIF-67

Abstract

  • Sintesis material komposit berpori ZIF-67/Kitosan telah berhasil dilakukan melalui metode in-situ dengan penambahan sebanyak 0,5 g kitosan dalam prekursor ZIF-67. Hasil analisa XRD menunjukkan tidak ada perubahan struktur kristal ZIF-67 setelah penambahan kitosan. Selain itu, spektra FTIR telah mengkonfirmasi adanya pembentukan puncak serapan gabungan dari kedua penusun material komposit, ZIF-67 dan kitosan yang menunjukkan keberhasilan sintesis komposit ZIF-67/Kitosan. Hasil kinerja adsorpsi zat warna metil jingga menunjukkan komposit ZIF-67/Kitosan memiliki kapasitas adsorpsi tertinggi sebesar 58,62 mg/g dengan persen penyerapan zat warna sebesar 29,31%. Hasil tersebut telah meningkat sebesar 381,67% dibandingkan dengan kitosan murni yang hanya sebesar 12,17 mg/g dengan persen penyerapan zat warna sebesar 6,08%. Modifikasi kitosan dengan ZIF-67 melalui metode sintesis sederhana telah mampu meningkatkan kinerja kitosan sebagai adsorben konvensional yang sangat signifikan.

Downloads

Download data is not yet available.

Author Biographies

Jumiatun, Politeknik Negeri Jember

Department of Agricultural Production, Politeknik Negeri Jember

Badrut Tamam Ibnu Ali , National Research and Innovation Agency, B.J. Habibie Building, Central Jakarta, Indonesia

National Research and Innovation Agency, B.J. Habibie Building, Central Jakarta, Indonesia

References

[1] R. Ediati et al., “Chitosan/UiO-66 composites as high-performance adsorbents for the removal of methyl orange in aqueous solution,” Mater. Today Chem., vol. 21, hal. 100533, 2021, doi: 10.1016/j.mtchem.2021.100533.

[2] A. Dajic, M. Mihajlovic, S. Mandic-Rajcevic, D. Mijin, M. Jovanovic, dan J. Jovanovic, “Improvement of the Textile Industry Wastewater Decolorization Process Using Capillary Microreactor Technology,” Int. J. Environ. Res., vol. 13, no. 1, hal. 213–222, 2019, doi: 10.1007/s41742-018-0162-3.

[3] M. S. Derakhshan dan O. Moradi, “The study of thermodynamics and kinetics methyl orange and malachite green by SWCNTs, SWCNT-COOH and SWCNT-NH2 as adsorbents from aqueous solution,” J. Ind. Eng. Chem., vol. 20, no. 5, hal. 3186–3194, Sep 2014, doi: 10.1016/j.jiec.2013.11.064.

[4] K. Wang, X. Tao, J. Xu, dan N. Yin, “Novel chitosan-MOF composite adsorbent for the removal of heavy metal ions,” Chem. Lett., vol. 45, no. 12, hal. 1365–1368, 2016, doi: 10.1246/cl.160718.

[5] H. Alyasi, H. Mackey, dan G. McKay, “Adsorption of Methyl Orange from Water Using Chitosan Bead-like Materials,” Molecules, vol. 28, no. 18, 2023, doi: 10.3390/molecules28186561.

[6] X. X. Liang, N. Wang, Y. Le Qu, L. Y. Yang, Y. G. Wang, dan X. K. Ouyang, “Facile preparation of metal-organic framework (MIL-125)/chitosan beads for adsorption of Pb(II) from aqueous solutions,” Molecules, vol. 23, no. 7, 2018, doi: 10.3390/molecules23071524.

[7] S. Kaskel, The Chemistry of Metal-Organic Frameworks, Volume 1. Germany: Wiley-VCH, 2016.

[8] R. Ediati, P. Elfianuar, E. Santoso, D. Oktavia Sulistiono, dan M. Nadjib, “Synthesis of MCM-41/ZIF-67 Composite for Enhanced Adsorptive Removal of Methyl Orange in Aqueous Solution,” in Mesoporous Materials - Properties and Applications, P. Elfianuar, Ed. Rijeka: IntechOpen, 2019, hal. Ch. 3.

[9] D. O. Sulistiono dan R. Ediati, “Synthesis of ZIF-67 in the presence of acetic acid as methyl orange adsorbent,” 4Th Int. Semin. Chem., vol. 2349, hal. 020067, 2021, doi: 10.1063/5.0052106.

[10] N. L. Torad et al., “Direct synthesis of MOF‐derived nanoporous carbon with magnetic Co nanoparticles toward efficient water treatment,” Small, vol. 10, no. 10, hal. 2096–2107, 2014.

[11] K. Zhou, B. Mousavi, Z. Luo, S. Phatanasri, S. Chaemchuen, dan F. Verpoort, “Characterization and properties of Zn/Co zeolitic imidazolate frameworks vs. ZIF-8 and ZIF-67,” J. Mater. Chem. A, vol. 5, no. 3, hal. 952–957, 2017, doi: 10.1039/C6TA07860E.

[12] R. Banerjee, “High-Throughput Synthesis of Zeolitic,” ReVision, vol. 939, no. February, hal. 939–944, 2008.

[13] H. Yan et al., “Solution growth of NiO nanosheets supported on Ni foam as high-performance electrodes for supercapacitors,” Nanoscale Res. Lett., vol. 9, no. 1, hal. 1–7, 2014, doi: 10.1186/1556-276X-9-424.

[14] R. Zhao, T. Ma, S. Zhao, H. Rong, Y. Tian, dan G. Zhu, “Uniform and stable immobilization of metal-organic frameworks into chitosan matrix for enhanced tetracycline removal from water,” Chem. Eng. J., vol. 382, no. September, hal. 122893, 2020, doi: 10.1016/j.cej.2019.122893.

[15] Y. Wang, X. Dai, Y. Zhan, X. Ding, M. Wang, dan X. Wang, “In situ growth of ZIF-8 nanoparticles on chitosan to form the hybrid nanocomposites for high-efficiency removal of Congo Red,” Int. J. Biol. Macromol., vol. 137, hal. 77–86, 2019, doi: 10.1016/j.ijbiomac.2019.06.195.

[16] X. Li, X. Gao, L. Ai, dan J. Jiang, “Mechanistic insight into the interaction and adsorption of Cr(VI) with zeolitic imidazolate framework-67 microcrystals from aqueous solution,” Chem. Eng. J., vol. 274, no. Vi, hal. 238–246, 2015, doi: 10.1016/j.cej.2015.03.127.

[17] Q. Li, J. Guo, H. Zhu, dan F. Yan, “Space-Confined Synthesis of ZIF-67 Nanoparticles in Hollow Carbon Nanospheres for CO 2 Adsorption,” Small, vol. 15, no. 8, hal. 1–8, 2019, doi: 10.1002/smll.201804874.

[18] Y. Jiang et al., “Cross-linked chitosan/β-cyclodextrin composite for selective removal of methyl orange: Adsorption performance and mechanism,” Carbohydr. Polym., vol. 182, hal. 106–114, Feb 2018, doi: 10.1016/j.carbpol.2017.10.097.

[19] Z. Hasan dan S. H. Jhung, “Removal of hazardous organics from water using metal-organic frameworks (MOFs): Plausible mechanisms for selective adsorptions,” J. Hazard. Mater., vol. 283, hal. 329–339, Feb 2015, doi: 10.1016/j.jhazmat.2014.09.046.

[20] Z. Zhang, J. Zhang, J. Liu, Z. Xiong, dan X. Chen, “Selective and Competitive Adsorption of Azo Dyes on the Metal–Organic Framework ZIF-67,” Water, Air, Soil Pollut., vol. 227, no. 12, hal. 471, Des 2016, doi: 10.1007/s11270-016-3166-7.

Downloads

Published

2025-05-06

How to Cite

Sulistiono, D. oktavia, Jumiatun, J., & Tamam Ibnu Ali , B. (2025). Modification of Porous Composite Material ZIF-67/Chitosan as Methyl Orange Dye Absorbent : Modifikasi Material Komposit Berpori ZIF-67/Kitosan sebagai Penyera Zat Warna Metil Jingga. Jurnal Ilmiah Inovasi, 25(1), 13–19. Retrieved from https://publikasi.polije.ac.id/jii/article/view/5855

Issue

Section

Article